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Posts by Bill The Chemist

Oh don’t worry once I stopped freaking out I immediately texted him.

1 year ago 2 0 0 0
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“Excuse me sir has anyone ever told you that you look just like Sidney Crosby?”

1 year ago 17 0 1 0

Kind of want to get active on social media again but rebrand as a buff scientist or something

1 year ago 3 0 1 0

I’ve already read 6 books in 2025! Feels so nice to have more free time for reading!

1 year ago 2 0 0 0

Chemsky meets survivorsky discourse!? Any season with Parvati Shallow is a fave of course. Vanuatu and Philippines are also faves of mine. In the new era I’ve also really enjoyed 42,44,45,and 46! (Post-Covid every season has been great)

1 year ago 2 0 1 0
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Biomimetic Synthesis of Azorellolide via Cyclopropylcarbinyl Cation Chemistry A concise synthesis of the complex diterpene azorellolide, inspired by speculations on biosynthetic cationic cascades, is presented. The approach, guided by computation, relies on the intramolecular i...

Biomimetic cation rearrangements from @dirktrauner.bsky.social and his phenomenal student Jordan! Love seeing computations aiding synthetic strategies! A really great story and impressive chemistry! pubs.acs.org/doi/10.1021/...

1 year ago 7 0 0 0

Did you know? Black Friday is named in honor of Rebecca Black, who invented Friday in 2011.

1 year ago 41417 11330 523 433

My cousin casually mentioning she’s about to do undergrad research in total synthesis 🫢

1 year ago 12 0 4 0
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Three-Component Synthesis of Multiply Functionalized 5,6-Dehydroisoquinuclidines through Dearomatization of Pyridine A three-component synthesis of multiply functionalized 5,6-dehydroisoquinuclidines is described. After the formation of an N-alkylpyridinium salt, Grignard addition led to the formation of the corresp...

So in one of my papers I demonstrated this same sequential Grignard/Diels-Alder transformation. Nice to see this chemistry more thoroughly explored here! pubs.acs.org/doi/10.1021/...

1 year ago 13 0 0 0

And if I could talk to my 16 year old self I would tell him it gets better. (I parallel parked on the busiest street in my hometown without crying)

1 year ago 4 0 0 0
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RIP Suze. 2007-2024

1 year ago 3 0 1 0
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If you like total synthesis and Wordle, check out Synthordle, a retrosynthetic analysis game created by Shenvi Lab associates Kevin Zong (GS 2) and Jonah Luo (HS sophomore!).
shenvilab.github.io/Synthordle/
Easy problems for Sophomore OChem, hard problems for advanced practitioners.

1 year ago 98 29 9 11
stable aminal vs. stable animal

stable aminal vs. stable animal

Do not confuse...

1 year ago 174 29 4 5
https://pubs.acs.org/doi/10.1021/acs.accounts.9b00539

And of course, the Baran lab guide that coined “electrocurious” t.co/WYo0j8aQFQ

1 year ago 2 0 0 0
https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/celc.202400193?af=R

HTE meets echem meets hypervalent iodine meets McGill? This was written with me as the target audience specifically but I’ll share it with yall too. t.co/1C7Kjl51TB

1 year ago 0 0 1 0

Another handy guide on electrode materials iopscience.iop.org/article/10.1...

1 year ago 2 0 1 0
https://pubs.acs.org/doi/10.1021/acs.chemrev.7b00656

Physical organic chemistry principle in synthetic echem! t.co/udQ5j9x38z

1 year ago 2 0 1 0
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https://pubs.acs.org/doi/10.1021/acs.jchemed.7b00361

A fantastic J Chem Ed on cyclic voltammetry t.co/Wa8cJaojFn

1 year ago 2 0 1 0
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Electrode Materials in Modern Organic Electrochemistry The choice of electrode material is critical for achieving optimal yields and selectivity in synthetic organic electrochemistry. The material imparts significant influence on the kinetics and thermod...

One of the most common questions I get is “how do you pick what kind of electrodes to use?” The answer: with help from literature! Different materials are better for different things. onlinelibrary.wiley.com/doi/full/10....

1 year ago 2 0 1 0
https://pubs.rsc.org/en/content/articlelanding/2014/CS/c3cs60464k

Little’s guide to redox mediators for when direct electrolysis is not ok t.co/K7tQJyiZrI

1 year ago 2 0 1 0
https://pubs.acs.org/doi/full/10.1021/acs.joc.1c01520

Stahl’s guide on how to think about voltage and overpotential t.co/hTe0LhLfr1

1 year ago 2 0 1 0
Solvent Control in Electro-Organic Synthesis Thieme E-Books & E-Journals

Remember when you made your SN1/SN2/E1/E2 flowchart in sophomore organic? This is that but with echem solvent effects from Waldvogel www.thieme-connect.de/products/ejo...

1 year ago 2 0 1 0
Making electrochemistry easily accessible to the synthetic chemist - Green Chemistry (RSC Publishing) DOI:10.1039/D0GC01247E

Willans guide on making echem accessible for organic chemists. Closing the knowledge gap between hardcore electrochemists and novice organic folks who want to zap molecules pubs.rsc.org/en/content/a...

1 year ago 4 0 1 0
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A practical guide to electrosynthesis - Nature Reviews Chemistry The aim of this Review is to guide synthetic chemists through their first electrosyntheses by describing the essential aspects of the field and by sharing practical tips. The fundamentals of electroan...

An excellent guide with case studies from Lam and Leech. Perfect for anyone who might be electrocurious to get their feet wet! www.nature.com/articles/s41...

1 year ago 2 0 1 0

Hi everyone! I figure I should make my thread about “how the heck did I learn echem” so buckle up and hold onto your electrasyn!

1 year ago 17 1 1 1
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I’m sorry but how dare you imply a podcast about a show that’s been off the air for almost 20 years is “alienating niche”

1 year ago 1 0 0 0
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I guess #chemsky is here now? Stay tuned for an unboxing video!

1 year ago 5 0 1 0

Organic chemists be like “I know a spot” and it’s a messy TLC they are convinced they can separate without a prep plate… or it’s Bluesky! (First post here the same as my first ever tweet)

2 years ago 9 0 2 0