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Posts by Jessica Schiffman

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Developing Design Rules for Polyelectrolyte Complex Materials: Role of Polyelectrolyte Length, Charged Group, and Backbone Polyelectrolyte complexation is an entropically driven, associative phase separation that has been leveraged to produce aqueously processed plastics known as polyelectrolyte complexes (PECs). Previous...

Are you interested in glass transitions in polyelectrolyte complexes? Check out these two new papers published in @pubs.acs.org Macromolecules by Isaac Ramírez Marrero
and our collaborators in UMass PSE and @basf.bsky.social!
doi.org/10.1021/acs....
doi.org/10.1021/acs....

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Promotional graphic with the text: ‘Call for Papers. ACS Applied Bio Materials. Antimicrobial and Antibiofilm Biointerfaces. Submit Your Manuscript’

Promotional graphic with the text: ‘Call for Papers. ACS Applied Bio Materials. Antimicrobial and Antibiofilm Biointerfaces. Submit Your Manuscript’

This Special Issue will collect high quality contributions in antimicrobial biointerfaces research.

Submit your manuscript by June 1, 2026: buff.ly/r1Uu6IU

5 days ago 1 1 0 0
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“This is an incredibly painful moment for the Hampshire community, and we are doing everything to support our students in completing their studies and assist our faculty and staff in navigating what comes next.“ — President Jennifer Chrisler

www.hampshire.edu/closure-info...

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Rapid Stabilization and Linear Superelasticity Mediated by Semicoherent Interfacial Architecture in NiTi Shape Memory Alloys NiTi shape memory alloys possess outstanding superelasticity and functional recoverability, but their widespread application is constrained by slow stabilization and fatigue accumulation during mechanical training, often requiring hundreds of cycles. In this work, we designed a high-stability NiTi composite by engineering grain-boundary chemistry and interface structure. Using low-energy ball milling followed by spark plasma sintering, a quaternary Ti–Ni–Si–C phase forms in situ and self-organizes into a continuous grid-like network along grain boundaries. This phase exhibits a semicoherent interface with the B2 NiTi matrix phase, featuring partial lattice matching and periodic misfit dislocations. As a result, the composite rapidly stabilizes after only five cycles and demonstrates linear superelasticity of 10,000 compression cycles at 2% strain, with progressively reduced hysteresis. Meanwhile, the introduction of the Ti–Ni–Si–C and TiC phases, along with refined Ni4Ti3 precipitates, doubles the hardness from ∼250 to ∼500 HV1. This interface-guided phase design provides a general strategy for developing NiTi-based materials with rapid training, enhanced fatigue resistance, and improved mechanical robustness for advanced actuation and structural applications.

Happy Friday - enjoy this Fresh ASAP in ACS Applied Engineering Materials!

Rapid Stabilization & Linear Superelasticity Mediated by Semicoherent Interfacial Architecture in NiTi Shape Memory Alloys

pubs.acs.org/doi/10.1021/...

1 week ago 0 0 0 0
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Passive Solar Heat Transfer via Photothermal Skins for Capability-Enhancing Building Retrofits Rising energy costs in dwellings cause a significant negative social impact, creating energy insecurity. In the United States, over 33 million homes report forms of energy insecurity, with over 24 mil...

Congrats to my @umassamherst.bsky.social colleagues on this lovely collaborative manuscript published in the March 2026 issue of ACS Applied Engineering Materials

Passive Solar Heat Transfer via Photothermal Skins for Capability-Enhancing Building Retrofits
pubs.acs.org/doi/10.1021/...

3 weeks ago 2 0 0 0
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🕷️ Inspired by Spiders 🕸️

From Spherulites to Strain-Induced Crystals: Process-Driven Crystallinity in Melt Electrospinning Writing of Polycaprolactone

New ASAP in ACS Applied Engineering Materials - Congrats to the authors 🎊
pubs.acs.org/doi/10.1021/...

1 month ago 2 1 0 0
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Using Electric Fields for in Situ Curing of Carbon Fiber/Phenolic Composites in Additive Manufacturing In this paper, we demonstrate electrothermal heating and curing of carbon fiber (CF)/phenolic composites to enable successive deposition for additive manufacturing (aka 3D printing). Electric fields a...

Happy Friday 🎉

Today’s ASAP ACS Applied Engineering Materials highlight is led by Prof. Micah Green @tamu.bsky.social

Using Electric Fields for in Situ Curing of Carbon Fiber/Phenolic Composites in Additive Manufacturing
pubs.acs.org/doi/10.1021/...

Congrats to all authors!

1 month ago 2 1 0 0
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Aqueous Processing of Mechanically Robust, Dense Films from Carboxymethyl Cellulose-Based Coacervates This study fabricates free-standing films from the natural polyanion carboxymethyl cellulose (CMC) paired with the synthetic polycation poly(diallyldimethylammonium chloride) (PDADMAC) using all-aqueous processing. First, the ability of CMC and PDADMAC to form polyelectrolyte complexes (PECs) in the presence of sodium chloride (NaCl) or potassium bromide (KBr) was screened by using turbidity measurements. This revealed that an excess of polycations was required to induce coacervation in CMC/PDADMAC in the presence of either salt, which amassed a net positive charge in the coacervates. The optimized PEC conditions for casting were corroborated via rheological testing, which indicated higher coacervate sensitivity to KBr than to NaCl. Next, blade casting was used to spread the coacervates into a thin layer, which were processed into films using aqueous phase separation (APS). The morphology, thermal properties, and mechanical performance of the films were evaluated by using scanning electron microscopy (SEM), dynamic mechanical analysis (DMA), and tensile testing, respectively. SEM revealed that the films were dense, with Young’s moduli ranging from 436 to 975 MPa. Higher salt concentrations in the coacervates yielded films with fractured and unstable surfaces, which resulted in a significant decrease in mechanical strength, though the films were still robust with Young’s moduli ranging from 110 to 330 MPa. With the knowledge that our CMC/PDADMAC films were manufactured with an excess of PDADMAC, we hypothesized that their cationic nature would result in intrinsic antimicrobial properties via contact killing. Indeed, all CMC/PDADMAC films inactivated ∼50% of the Escherichia coli and Staphylococcus aureus, supporting that the manufactured films present free cationic groups available to kill microbes or further chemical modifications. We suggest that these high-strength biopolymer-based films produced via sustainable all-aqueous processing hold potential for use as membranes, packaging materials, and high-touch coatings.

Congrats to Bren on their premiere first author paper! 🎉

Aqueous Processing of Mechanically Robust, Dense Films from Carboxymethyl Cellulose-Based Coacervates

ASAP in ACS Applied Polymer Materials

pubs.acs.org/doi/10.1021/... @pubs.acs.org

1 month ago 2 1 0 0
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🧐 Check out our Editorial on Additive Manufacturing to Advance Clean Technology
pubs.acs.org/doi/10.1021/...

Thanks to Editors Marcus Worsley & Jeremy Feaster @berkeleylab.lbl.gov & Yat Li (UC SantaCruz)

See also the Full Issue on AM in ACS Appl Eng Materials!
pubs.acs.org/page/aaemdr/...

1 month ago 2 0 1 0
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So excited that Sarthak Saha was awarded the 2024 UMass Chemical and Biomolecular Engineering Best Dissertation Award for his research on "Advanced Microfluidics Platforms for Protein Crystallization and X-ray Crystallography"!

1 month ago 4 1 0 0
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Phase-Change Polymer–Metal Composites with Tunable Thermal Conductivity and Their Additive Manufacturing Polymer–metal composites that combine a soft polymer matrix with low-melting-point metal/alloy particles that can be melted within a compatible temperature range hold great promise for multifunctional additive manufacturing (AM). The reversible melting–solidification phase transition of the metal component, coupled with the mechanical flexibility and stretchability of the polymer matrix, enables thermally responsive and mechanically tunable composites suitable for 3D printing. However, a fundamental understanding of their thermal, rheological, and morphological behaviors remains limited. In this work, we investigate a series of polymer–metal composites composed of Field’s metal (FM) and thermoplastic elastomers (TPE), with the goal of elucidating the critical structure–property relationships for material extrusion-based AM. Thermo-rheological analyses reveal distinct temperature-dependent transitions strongly influenced by FM content and processing conditions. X-ray diffraction and electron microscopy further demonstrate significant process-dependent morphological evolution. Notably, these composites exhibit highly tunable thermal conductivity, achieving values up to 19 W m–1 K–1 after the postprinting processing. Successful 3D printing via pellet extrusion reveals substantial differences in thermal, rheological, and mechanical properties compared to solution-cast counterparts, primarily due to shear-induced morphological rearrangement during printing. The insights gained into the key structure–property relationships of these 3D-printable multifunctional FM–TPE composites pave the way for their potential applications in thermal management, soft electronics, and robotics.

Friday reading from ACS Applied Engineering Materials 🤓

Phase-Change Polymer–Metal Composites with Tunable Thermal Conductivity and Their Additive Manufacturing

pubs.acs.org/doi/10.1021/...

2 months ago 3 1 0 0
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📣We have a new Associate Editor at ACS Applied Eng Materials!

Welcome to the team Prof. Douglas Galvão from the State Univ of Campinas @unicampoficial.bsky.social

🤝 Galvão’s research spans computational & applied materials exemplifying theory–experiment synergy that our journal champions.

2 months ago 3 0 0 0
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🆕 ASAP on 3D Printing of Microalgae from Caltech in ACS Applied Engineering Materials

Preserving Microstructure Enhances Cohesion & Mechanical Performance in Spirulina-Based 3D-Printed Biomaterials

pubs.acs.org/doi/10.1021/...

2 months ago 2 1 0 0
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The January 2026 issue of ACS Applied Engineering Materials is live and features work led by Dr. Kottapalli from Univ Groningen on the cover!

👣 Wearable Sensors for Spatiotemporal Gait Analysis Using Electrospun Piezocapacitive Insoles 👣

pubs.acs.org/doi/10.1021/...

@acs.org @pubs.acs.org

2 months ago 1 1 0 0
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PMSE Student Travel Award - Applications for the Atlanta, GA ACS Meeting are Due 1/30/26 The PMSE Division is providing up to two (2) $500 travel awards to students presenting at the ACS National Meeting Eligibility: PMSE Members who identify as female and/or who are under-represented…

🚨 Grad Student Travel Awards - Spring 2026 ACS Meeting 🚨
The ACS PMSE Division is offering two $500 travel awards for grad students attending & presenting in PMSE symposia at the Spring 2026 ACS Meeting (Atlanta, GA).
🗓 Apply by 1/30/26
🔗 Info & Application: forms.gle/HCMR7ReeZNN2...
#ACSSpring2025

3 months ago 0 2 0 0
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#Wrapped2025 ⭐ Thanks to our Authors, Reviewers, Editors, Advisory Board, & Staff! We had an Awesome Third Year @ ACS Applied Engineering Materials! ⭐

#chemsky @acs.org @pubs.acs.org @acspmse.bsky.social

pubs.acs.org/journal/aaemdr

3 months ago 6 0 0 0
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the Dec 2025 Issue of ACS Applied Engineering Materials features work led by Prof. Xiao Li @ the Univ of North Texas!

Phase Separation of Homopolymer-Blended Liquid Crystal Elastomer for Creation of Porous Structures 🧽

pubs.acs.org/doi/10.1021/...

Cheers 🥂

3 months ago 1 1 0 0
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Cationically Modified PVA-Based Electrospun Nanofiber Membrane for Adsorptive PFAS Removal from Water Per- and polyfluoroalkyl substances (PFAS), a diverse range of anthropogenic organic compounds, pose significant concerns to society due to their potential harmful impacts on human health and ecosyste...

If the weather outside is frightful, we better collect PFAS...

Cationically Modified PVA-Based Electrospun Nanofiber Membrane for Adsorptive PFAS Removal from Water

New ASAP in ACS Applied Engineering Materials

pubs.acs.org/doi/10.1021/...

4 months ago 3 0 0 0
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AY25-26 Chemical Engineering Faculty Jobs List

The 2026 Chemical Engineering Faculty Jobs List (run by Arvind Ganesan and Todd N. Whittaker) has 92 research/teaching positions and 19 teaching-only positions: docs.google.com/spreadsheets... #facultychemEjobs

4 months ago 4 6 0 0
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Congratulations to ✨Doctor ✨ Shao-Hsiang (Joe) Hung!!

4 months ago 7 1 0 0
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Polydimethylsiloxane gel thickness and stiffness affect the initial adhesion of Escherichia coli and Staphylococcus aureus The persistent presence of hospital-acquired bacterial infections and the growing prevalence of antibiotic-resistant bacterial strains necessitates a greater understanding of the initial adhesion of b...

ASAP Article! Thickness & Stiffness of PDMS influences the adhesion of microbes

Congrats to a stellar @schiffmanlab.bsky.social team incl: grad students Brandon & Meng-Chen along w/fantastic undergrads Dylan & Uzo!

Now published in RSC Applied Polymers!

pubs.rsc.org/en/content/a... @rsc.org

4 months ago 2 1 0 0
Promotional graphic with headshot of Prof. Suzana Nunes and the text: ‘Industry Webinar. ACS Expert Session. From Bio-Based Solvents to Circular Polymers: Pathways Toward Sustainable Membrane Technology’

Promotional graphic with headshot of Prof. Suzana Nunes and the text: ‘Industry Webinar. ACS Expert Session. From Bio-Based Solvents to Circular Polymers: Pathways Toward Sustainable Membrane Technology’

Join us for this special industry webinar exploring cutting-edge research in green biopolymers and sustainable membrane technologies.

🗓️ Tuesday, December 9, 2025
🕘 09:00–10:00 BRT | 07:00–08:00 EST | 15:00–16:00 AST

🔗 Register now: buff.ly/ma0n26k

4 months ago 2 1 0 0
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Check out the #ACS booth number 805 at the exhibition of the #F25MRS conference and learn about publishing with ACS - you can meet me in the lunch break and talk about the #ACS #Applied #Materials & #Interfaces #journal (@ACS_AMI)

4 months ago 2 1 0 0
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Solar Reforming: Sunlight-Driven Waste to Chemicals for a Bright Future

Interested in 🌞Solar Reforming: Sunlight-Driven Waste to Chemicals for a Bright Future?🌞

Then see our new ➡️ Editorial & Manuscript Collection in ACS Applied Engineering Materials!

Thanks to Prof. Stuart Linley @ McMaster for leading this effort!

pubs.acs.org/doi/10.1021/... @pubs.acs.org

4 months ago 2 0 0 0
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Some of the ✨beautiful✨ covers for the November 2025 Issue of ACS Applied Engineering Materials!

pubs.acs.org/toc/aaemdr/c...

Thankful to all of our authors, readers, & reviewers!

4 months ago 3 1 0 0
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Tiny, semipermeable magnetic spheres could allow microbial cultures to grow in soil or ocean water before being collected later. cen.acs.org/biological-c...

#chemsky 🧪

4 months ago 5 2 1 0
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Dual-Functional Triphenyltriindole “Knitting Polymers” for Efficient Iodine Capture and Zn–I2 Batteries This work introduces a class of nitrogen-rich porous polymers synthesized via “knitting polymerization” using a redox-active triphenyltriindole monomer. Two synthetic routes-thermal Friedel–Crafts rea...

Happy Friday reading 🤓 from ACS Applied Engineering Materials!

The team led by Drs María Luisa Ferrer & Berta Gómez-Lor (ICCMM Spain) knit polymers into batteries! 🧶🔋

pubs.acs.org/doi/10.1021/...

5 months ago 2 0 0 1

The 2025-2026 BME TT Faculty jobs list has 87 positions. #FacultySearch #BME #BMEJobsList

Add a job: forms.gle/bwEzwHAEehBj...
Jobs list: ericaprattlab.com/bme_jobs_list/

5 months ago 3 6 0 0
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📣 The Schiffman Lab is looking to hire a Postdoctoral Researcher with experience in #membranes and #polymers. Interested candidates should email me their resumes and a statement of interest. Hope to chat #AIChE!

5 months ago 1 0 0 0
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Aqueous Processing of Stoichiometric and Nonstoichiometric Materials from Complex Coacervates ConspectusWith the rise of green engineering, there is an increasing need to manufacture materials without relying on organic solvents. Using all-aqueous approaches mitigates the industrial safety and...

🔥Off the Press - Congrats Joe!! Our lab's 1st publication in Accounts of Materials Research @pubs.acs.org

Aqueous Processing of Stoichiometric and Nonstoichiometric Materials from Complex Coacervates
pubs.acs.org/doi/full/10....

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