A Bis(germaamidine) through Nitrene Insertion into GeSi Bonds Nitrene insertion into the Ge<span class='icomoon'></span>Si bonds of masked bis(germylene)s is followed by nitrene addition to the Ge(II) centers to provide a bis(germaamidine) with GeN bonds bridged via a σ,π-conjugated amin...

Another exciting 🧩 on the bifunctional monomers for our poly(digermene)s: nitrene insertion into the Ge-Si bonds provides a bis(germaamidine)! doi.org/10.1002/zaac... - dedicated to @akmeyergoettingen.bsky.social and @christianlimberg.bsky.social on the occasion of their 60th birthdays

The Flexible Behaviour of a Trigonal Arylimido Iron Complex A trigonal arylimido iron complex is reported which is found in an intermediate spin state. The iron bound imido unit is electronically flexible and acts as nucleophile, reductant, or H atom abstracto...

Happy to announce our newest imido iron compound in @chemcomm.rsc.org : pubs.rsc.org/en/content/a....
It was a very tedious work with a lot of headscratching in-between due to its high reactivity (hmds co-ligands!)...In cooperation with @akmeyergoettingen.bsky.social and @cutsail-lab.bsky.social.

Many congratulations to our own Isabelle for successfully defending her PhD thesis yesterday! 🥳🥳🥳

#PhDone #chemsky

Thanks @daumannl.bsky.social , we're happy to have joined the #chemsky community! 🥳