Opposite Effects of Added AsPh3 Reveal a Drastic Mechanistic Switch in RhI/AuI Transmetalations via Rh–Au Bonded Intermediates | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Peñas-Defrutos, Espinet, & co-workers @InorgChem #AsPh3 #gold #rhodium #microkinetic #DFT #transmetalation

Synthesis and Photophysics of the Doubly Cyclometalated Pd(II) Complexes [Pd(C∧N∧C)(L)], L = PPh3, AsPh3, and SbPh3 | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Dietzek-Ivanšić, Strassert, Klein, and co-workers @InorgChem #palladium #CNC #PPh3 #AsPh3 #SbPh3 #photoluminescence