A simple, scalable method by Jurk & van Gemmeren @vangemmerenlab.bsky.social to convert secondary sulfonamides into sulfonyl fluorides using affordable #DAST ⚗️, yielding excellent results! These sulfonyl fluorides readily couple with amines to create diverse libraries.
#SuFEx

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Dive into the fascinating world of Sulfur(VI) fluoride exchange #SuFEx chemistry and explore the latest development of direct #fluorosulfonylation with fluorosulfonyl radicals🧪This review by Li and Wang highlights key radical precursors like FSO₂Cl

👉 buff.ly/eYfwR1J

Xu, Dong and co-workers report the use of NH-sulfamoyl fluorides (RNHSO₂F) as reliable #SuFEx synthons for constructing sulfamate esters! Using KF as a base, azasulfene intermediates were generated, enabling efficient ligation with phenols & alcohols 🔬

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#SuFEx chemistry turns 10 🎂 Explore a decade of innovation, from efficient polymerizations to groundbreaking radiochemistry. Read the latest review by Chun, Hong and co-workers and discover the future of SuFEx chemistry 🧪

👉 https://buff.ly/4hN9lXf

What's the future of metal-free #clickchemistry? 🤔 Discover the power of #SuFEx! Explore the latest advancements and learn about the potential of sulfur(VI)-fluoride exchange reactions in our review by Renzo Luisi's group.

#OpenAccess 👉 www.thieme-connect.com/products/ejo...