#Tetraethynylmethane: a rare, thermally unstable building block that’s fascinated chemists for decades🧪 Sebastian Beil @sebastianbeil.bsky.social report its synthesis and initial use in porous materials, though its full potential remains untapped🌟
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💥Systematic study of nitrogen heterocycles by Samuel Oger & Gwilherm Evano! Cu-photoredox catalysis + blue light drives exo-dig radical cyclizations of sulfonamides → azetidines, pyrrolidines, piperidines & azepanes💡
#copper #photoredox #alkynes
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IPr*diNHC: Sterically Adaptable Dinuclear N-Heterocyclic Carbenes | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Szostak, Bisz, and co-workers @InorgChem #NHCs #dinuclear #steric #electronic #IPrstar #gold #catalysis #hydration #carboxylation #alkynes
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