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Brønsted acid-catalyzed synthesis of trifluoromethylated azulenes via cyclization of 1-phenyl-2-CF3-1,3-enynes Azulene and its derivatives are important scaffolds with broad applications. The introduction of a trifluoromethyl group is an efficient way to enhance the activity and physicochemical properties of d...

Research article by Yuhan Zhou's team.
#DLUT

Authors report a simple, Brønsted acid-catalyzed, intramolecular annulation of 1-phenyl-2-CF3-1,3-enynes for the efficient construction of valuable trifluoromethyl-substituted azulenes.

doi.org/10.1039/D5QO01617G