Hydride Transfer Reactivity of an Open-Shell [Fe3H]− Cluster We report herein the synthesis and reactivity of the high-spin iron-hydride cluster [K(C222)][(tbsL)Fe3(μ3–H)]. Direct hydride transfer reaction attempts led to cluster reduction to afford the anionic...

Congrats to Lisa & Ivan #BetleyGroup #HarvardCCB
🎉 The open-shell triiron #hydride cluster shows hydride-transfer reactivity toward isocyanides, alkynes & aldehydes. 😀😀 pubs.acs.org/doi/full/10....
@pubs.acs.org #crystallography #education

Unexpected Hydricity of a Bis-Carbene Iridium Complex Provides Insight into Electronic Structure Impacts on Hydride Donor Ability | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Miller and co-workers @InorgChem #iridium #carbene #bis_mim #hydricity #hydride #steric

Impact of Pendant Amine Basicity on Electrochemically-Promoted Cobalt Hydride Formation: Kinetic and Mechanistic Analysis | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Dempsey and co-workers @InorgChem #cobalt #hydride #amine #CO2 #PCET #H2

How Geometric Constraints Control the Hydride Position and Activity in [NiFe]-Hydrogenases and Their Biomimetic Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Niu and Hall @InorgChem #nickel #iron #hydrogenases #hydride #thiolate #CCSD #DFT #NBO #QTAIM

Amphoteric Zinc(II) Hydride Cations [ZnH]+: Effect of a Bipyridyl Ligand | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Englert, Kleemiss, Maron, Okuda, and co-workers @InorgChem #zinc #hydride #hydridic #protic #Me2bpy