Today two 3rd year students have the pleasure to make some PMe3 in their advanced inorganic lab course! Good job. @likat.bsky.social #31P

We present PhD No.4 from the group: Congrats Dr. Ayu! A splendid performance and a PhD period filled with laughter, lab curiosities and brilliant chemistry. Thanks Ayu and all the best for your future!

Also thanks @pchem.bsky.social for being on the committee. #phdone #proudpi #31p

Kushiks latest work on Carbazole-based bisPA ligands and aspects of their coordination chemistry with Rh(I) is now out @daltontrans.rsc.org Great work and thanks everyone for their help! #31p #phosphorus @likat.bsky.social

DFT Analysis of the 31P NMR Chemical Shift in C≡P Motifs | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Dong and Hinz @InorgChem #phosphorus #C_triplebond_P #diamagnetic #DFT #31P #NMR #NCS

Unofficial #HCCTWO
(1) #31P becoming more unlikely to redevelop

#wx #wxsky #cyclone

Unofficial #HCCTWO
(1) #31P could redevelop

#wx #wxsky #cyclone

Unofficial #HCCTWO
(1) #31P no longer a TC, could redevelop
(2) #Kanto failed to develop
(3) #99S not expected to develop

#wx #wxsky #cyclone

Unofficial #HCCTWO
(1) #31P meandering in the Gulf of Carpentaria
(2) A subtropical system could develop south of #Madagascar
(3) #99S not expected to develop

#wx #wxsky #cyclone

Unofficial #HCCTWO
(1) #31P weakens slightly
(2) #Errol nearly dissipated
(3) A subtropical system could develop south of #Madagascar
(4) #99S is out of time

#wx #wxsky #cyclone

Guter Punkt. War mir zudem nicht bewusst, dass auf USA Güter 61% Zoll ist. Zudem geht Zoll nach Gewicht, nicht nach Wert.
In 4 Jahren ist er wieder weg. In dieser Zeit kann man keine Produktion aufbauen.
#31p #bananenrepublik

Last month, I visited Innsbruck to attend #EWPC21 🇦🇹
I had an amazing time discussing my research and taking in the beauty of the Alps! I was even lucky enough to win the best session chair prize! 🏆
Thank you to all the organisers for holding a fantastic conference! #PhDlife #31P #chemsky

Flash Communication: Cyanophosphide Transfer Reactions Cyanophosphides of the general form [RPCN]− can be viewed as cyanide adducts of phosphinidenes and are phosphorus species in the (+1)-oxidation state. We have recently reported on the stable cyanophosphide [DippTerPCN]K (DippTer = 2,6-Dipp2C6H3, Dipp = 2,6-iPrC6H3) and now investigate its reactions with ECln (E = Ge, n = 2; E = P, As, n = 3) in either salt metathesis or base-assisted dehydrohalogenation reactions. In the case of GeCl2, salt metathesis with [DippTerPCN]K afforded the dimer of a chlorogermylene [DippTerP(CN)GeCl]2. When only 0.5 equiv of GeCl2 was used, the diphosphanylgermylene [DippTerP(CN)]2Ge was generated in solution. With ECl3 (E = P, As), facile cyanophosphide transfer was achieved from DippTerP(H)CN in NEt3-assisted dehydrohalogenation, giving diphosphanes or arsaphosphanes of the type DippTerP(CN)ECl2 (E = P, As), respectively.

Ayu is keeping it up! This piece is about ArPCN- transfer to give Germylenes and phosphapnictanes! Thanks @maltefischer.bsky.social and @fabiandankert.bsky.social for their help! Thanks Organomteallics for the smooth proceedings! #31p #phosphorus

pubs.acs.org/doi/10.1021/...

This would not have been possible without the hard work from Ayu, with amazing support from Edgar! Fabian Dankert did magic with the SCXRD data, Jonas Surkau carried out the IR/RAMAN studies and Andrey chipped in some CV-tricks. Great team effort! Congrats to everyone! #31P #phosphorus #ProudPI

Ayu just presented her work and some exciting cyanophosphide chemistry at the 21st EWPC in Inmsbruck! Great job!

Also a big shout out to the organizers Fabian Dielmann, Stephan Hohloch and their staff for organizing a wonderful conference!

#ewpc21 #31p #chemsky @likat.bsky.social

A BNAlP-heterocycle We report the [2+2]-cyclization reaction of a phosphaalumene with its lighter analog, an iminoborane, to give a species with a four-membered BNAlP-heterocycle with alternating Lewis basic and acidic c...

Our first post here.

Tim’s newest work on the reactivity of phosphaalumenes is out. When P=Al meets it’s smaller sibling a unique B,N,Al,P-heterocycle is formed. Congrats Tim and Leonie!
#chemsky @chemcomm.bsky.social @likat.bsky.social #31p

pubs.rsc.org/en/content/a...