Accessing phosphonioacetylide chemistry: isolable alkali metal precursors for rod-shaped carbon donor complexes Rod-shaped neutral carbon ligands such as carbon monoxide and isocyanides play a central role in organometallic chemistry but are relatively weak electron donors compared to N-heterocyclic carbenes. P...

Accessing phosphonioacetylide chemistry: isolable alkali metal precursors for rod-shaped carbon donor complexes

by Fabian Dielmann et al.

⚗️ Alkali metal phosphonioacetylides enable unique carbon donor complexes.

🔗 doi.org/10.1039/D5QI...

#Organometallics #LigandDesign #Chemistry

Ligand-modulated metallophilicity: influence of π-acceptor and σ-donor strength Metal–metal (M–M) closed-shell interaction, also known as metallophilicity, is frequently observed in d10 and d8 metal complexes featuring a close M–M distance. It has shown a significant impact on di...

Ligand-modulated metallophilicity: influence of π-acceptor and σ-donor strength
by Qingyun Wan et al.

π-acceptors reduce, while σ-donors enhance Pauli repulsion, tuning metallophilicity in closed-shell complexes ⚛️🔬📐

👉 doi.org/10.1039/D5QI...

#Metallophilicity ⚡ #LigandDesign 🧪

PhD position in structure-based RNA-ligand design (262809) | University of Bergen Job title: PhD position in structure-based RNA-ligand design (262809), Employer: University of Bergen, Deadline: Tuesday, May 21, 2024

#PhD position in structure-based #RNA #LigandDesign at University of Bergen (Norway) up to 4 years funding; starting August-2024; closing 21-May-2024 #CompChem #cheminformatics #CADD #SBDD #ChemPhD #chemsky 🧪
www.jobbnorge.no/en/available...