👇Don't miss the #OpenAccess research from Manuel Iglesias et al.
#Chemsky #Organic #OCFresearch

Organocatalytic asymmetric desymmetrization of cyclopentene-1,3-diones via a formal diaza–ene reaction with donor–acceptor hydrazones Herein we disclose a catalytic asymmetric desymmetrization of cyclopentene-1,3-diones via a formal diaza–ene reaction/tautomerization with donor–acceptor hydrazones. The H8-TRIP catalyst was found to ...

👇 #Research article by Subhas Chandra Pan and colleague from Indian Institute of Technology Guwahati

#Organocatalytic asymmetric desymmetrization of cyclopentene-1,3-diones via a formal diaza–ene reaction with donor–acceptor hydrazone

#Chemsky #Organic #OCFresearch

doi.org/10.1039/D5QO...

Cycloisomerization of 7-en-2-yn-1-ones to bicyclo[3.1.0]hexanes using electrophilic fluorination or chlorination agents In contrast to the π-electrophilic transition metal-catalyzed cycloisomerization of enynes, systematic studies on the reaction of enynes by activation of carbonyl groups conjugated to alkynes are lack...

🔊A recent research from Akio Saito et al. at Tokyo University of Agriculture and Technology

👉Cycloisomerization of 7-en-2-yn-1-ones to bicyclo[3.1.0]hexanes using electrophilic fluorination or chlorination agents

#Chemsky #Organic #OCFresearch

doi.org/10.1039/D4QO...

🏆Join us in celebrating another OCF Outstanding Paper Awards winner!

👉Pulsed electrolysis: enhancing primary benzylic C(sp3)–H nucleophilic fluorination
by Alastair J. J. Lennox et al. @bristoluni.bsky.social
#Chemsky #OpenAccess #Electrosynthesis #OCFresearch
doi.org/10.1039/D3QO...

🏆We are happy to present another OCF Outstanding paper by Xing-Zhong Shu et al. Congratulations to the authors!

👉Nickel-catalyzed dynamic kinetic cross-electrophile coupling of benzylic alcohols and alkenyl triflates
#chemsky #Organic #catalysis #OCFresearch

doi.org/10.1039/D3QO...

Dual-state emission of pyrazolyl-pyrrolo[3,4-b]pyridin-5-ones via excited-state intramolecular proton transfer (ESIPT): multicomponent synthesis and optical characterization The dual-state emission (DSE) phenomenon has become crucial for developing dual-state emission luminogens (DSEgens) that exhibit efficient luminescence in both solution and solid states, addressing th...

🔊A recent #research from Eduardo González-Zamora et al.

👉Dual-state emission of pyrazolyl-pyrrolo[3,4-b]pyridin-5-ones via excited-state intramolecular proton transfer (ESIPT): multicomponent synthesis and optical characterization
#Chemsky #OpenAccess #organic #OCFresearch

doi.org/10.1039/D4QO...

Photoredox copper-catalyzed regioselective syntheses of allenols via HAT-mediated propargyl radical generation Selectivity control of the reactions of propargylic and/or allenylic radicals remains particularly elusive. Here, a visible light-mediated Cu-catalyzed protocol for the highly selective syntheses of t...

👉Don't miss the #research article from our Editor-in-Chief, Shengming Ma.

#Photoredox copper-catalyzed regioselective syntheses of allenols via HAT-mediated propargyl radical generation
#Chemsky #Organic #OCFresearch
doi.org/10.1039/D4QO...

Enantioselective modular synthesis of α-aryl-α-heteroaryl aminonitriles with parts per million organocatalyst loading: mechanistic investigation for stereochemical origins Heteroaromatic installation and peripheral modifications are the most common reactions in the pharmaceutical industry. However, the synthesis of biologically important aminonitrile-functionalized hete...

👉Research article by Shuichi Nakamura et al

Enantioselective modular synthesis of α-aryl-α-heteroaryl aminonitriles with parts per million #organocatalyst loading: mechanistic investigation for stereochemical origins
#Chemsky #OCFresearch #Organic

🔗 doi.org/10.1039/D4QO...

🏆Join us in celebrating the OCF Outstanding Paper Awards winner!
👉"One-step synthesis of polycyclic thianthrenes from unfunctionalized aromatics by thia-APEX reactions"

🔗https://doi.org/10.1039/D2QO02058K

#Chemsky #Openaccess #Organic #OCFresearch

🏆Another OCF Outstanding Paper from Ang Li et al. at Shanghai Institute of Organic Chemistry

👉A concise total synthesis of sespenine, a structurally unusual indole terpenoid from Streptomyces
#Chemsky #Organic #OCFresearch #OpenAccess

🔗https://doi.org/10.1039/C5QO00416K