Maris Turks and co-researchers report a palladium-free #arylation strategy for #propargylsilanes, utilizing #diaryliodanes to trigger a sophisticated cascade sequence.

👉 https://tinyurl.com/4jzz4pfc 

#CopperCatalysis #ArylationReactions #iodanes #BJOC #DiamondOpenAccess 💎🔓

In this full research paper, the synthesis of N-doped chiral #macrocycles by regioselective palladium-catalyzed #arylation is described.
➡️ https://tinyurl.com/kwu6uvmp
#dihydroindolocarbazole #InherentChirality #nonplanarity 
#BJOC #DiamondOpenAccess 💎🔓

Mechanism of Gold-Catalyzed Arylation-Lactonization: A Density Functional Theory Study on the Role of the (MIC^N)AuCl Complex in Au(I)/Au(III) Catalysis pubs.acs.org/doi/10.1021/... Ribas, Pla-Quintana, Poater, and co-workers @InorgChem #gold #arylation #lactonization #DFT #catalysis

Palladium-Catalyzed Regioselective B(3,4,5,6)–H Tetra-Arylation of o-Carboranes | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Wu, Cao, Jiang, and co-workers @InorgChem #boron #palladium #carborane #arylation