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Pentacosaple-CO32− bridged hexacontaoctanuclear lanthanide-alkali barrels derived from octacosanuclear discs Phosphonate lanthanide carbonate cages are highly sought after in the development of multifunctional molecular-based materials due to their rigid framework and the inherent properties of metal ions. H...

🔥Pentacosaple-CO₃²⁻ bridged hexacontaoctanuclear lanthanide-alkali barrels derived from octacosanuclear discs by Li et al. 🛢️ Stepwise assembly of Dy₁₆K₁₂ → Dy₂₄Na₄₄ cages shows tunable supramolecular structure & magnetic relaxation. 🔗 doi.org/10.1039/D5QI...

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