Synthesis of a Keggin-type polyoxoselenidotungstate via site-selective oxygen-to-selenium substitution Selenium, a group 16 (chalcogen) element, can endow metal oxides with unique properties when replacing oxygen atoms from specific sites. Polyoxometalates (POMs), a class of anionic metal oxide cluster...

Our latest collaboration is now published in @chemicalscience.rsc.org featuring the first-ever fully terminal oxo-to-selenido substitution in a Keggin-type polyoxometalate!🎉
Check out the paper for all the details!
🔗
pubs.rsc.org/en/content/a...
#ChemSci #Polyoxometalates #POMspapers #POMs

Protonolysis and Condensation Reactions of Alkoxido-Substituted Lindqvist {MW5} and Keggin {MPW11} Polyoxometalates: Comparative Experimental and Modeling Studies An understanding of proton transfer and migration at the surfaces of solid metal oxides and related molecular polyoxometalates (POMs) and metal alkoxides is crucial for the development of reactivity i...

Happy to share out latest publication in Inorganic Chemistry! 🎉
pubs.acs.org/doi/10.1021/... @chemistryncl.bsky.social
#POMspapers #POMs

Mechanochemical Polyoxometalate Super-Reduction with Lithium Metal In this first systematic investigation of mechanochemical polyoxometalate (POM) reduction, (TBA)3[PMo12O40] was reacted with n equiv of lithium metal (n = 1–24) to generate PMo12/n products which were...

Exciting news! Our work published in JACS has already reached over 2,000 downloads!🎉 Haven't read it yet?
Check it out here 👇👇
pubs.acs.org/doi/10.1021/...
@chemistryncl.bsky.social
#POMs #POMspapers

Vanadium Substitution Dictates H Atom Uptake at Lindqvist-type Polyoxotungstates Understanding how modification of molecular structures changes the thermochemistry of H atom uptake can provide design criteria for the formation of highly active catalysts for reductive transformatio...

Our collaboration with @matsonlab.bsky.social looking at #PCET at the surface of vanadium-doped Polyoxotungstates is just out in Inorg. Chem.! pubs.acs.org/doi/10.1021/... #POMs #POMspapers