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A #PKUResearch team used the “cascade activation” approach to revive selenanthrene, a largely overlooked reagent, to enable direct C=C to C≡C transformation under mild conditions.

📖Published in @nature.com:
www.nature.com/articles/s41...

#PekingUniversity #AcademicSky #Stereochemistry #ChemSky

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Your Mom Is Trans (Isomer)

Your Mom Is Trans (Isomer)

Your Mom Is Trans (Isomer)

#Chemistry #Organicchemistry #Stereochemistry #Transisomer #Cisisomer

sciencehumor.io/chemistry-memes/your-mom...

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Unlock novel bioactives - Iain Coldham et la. describe the formation of #spirooxindoles using an intermolecular nitrone #cycloaddition reaction.
🔗 www.beilstein-journals.org/bjoc/articles/21/146
#cascade #oxindoles #spirocycle #stereochemistry
#BJOC 💎🔓

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Mirror Image Molecular Mayhem

Mirror Image Molecular Mayhem

Mirror Image Molecular Mayhem

#Chemistry #Chirality #Stereochemistry #Molecules #Pun

sciencehumor.io/chemistry-memes/mirror-i...

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Exquisite stereochemical control will allow creation of millions of unique polymers New method take inspiration from established techniques like those used to synthesise DNA

Exquisite stereochemical control will allow creation of millions of unique polymers #Science #Chemistry #MaterialsChemistry #Polymers #Stereochemistry #MaterialsScience

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The first articles of the thematic issue “Non-central #chirality in organic chemistry” edited by Ken Tanaka and Naohiko Yoshikai are online: 
➡️ https://tinyurl.com/4fb68xdj
More to come soon! 
#OrganicSynthesis #stereochemistry #asymmetric #stereoselective #catalysis #MaterialsScience #BJOC 💎🔓

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Submission to the thematic issue “Non-central #chirality in organic chemistry” edited by Ken Tanaka and Naohiko Yoshikai is still possible:
➡️ https://tinyurl.com/4fb68xdj
#OrganicSynthesis #stereochemistry #asymmetric #stereoselective #catalysis #MaterialsScience #BJOC 💎🔓

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Stereochemical editing used to tune explosive power of cage-like energetic materials Stereoisomers found to exhibit substantial differences in density, stability and detonation performance

Stereochemical editing used to tune explosive power of cage-like energetic materials #Science #Chemistry #MaterialsChemistry #Explosives #Stereochemistry #MaterialsScience

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The stereochemistry of substitution at S(VI) Since the re-birth of sulfur-fluoride exchange (SuFEx) chemistry, coined by Sharpless in 2014 as a ‘click’ reaction, the prevalence of sulfur(vi) moieties in medicinal, polymer and materials chemistry...

📘 The stereochemistry of substitution at S(VI) ✨
by James A. Bull 𝘦𝘵 𝘢𝘭.

Insights into stereochemical outcomes in SuFEx & S(VI) substitution ⚗️🔄

#SulfurChemistry #Stereochemistry #ClickChem
🔗 doi.org/10.1039/D5QO01043H

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There’s still time to submit your latest research to the thematic issue “Non-central #chirality in organic chemistry” edited by Ken Tanaka and Naohiko Yoshikai.
➡️ https://tinyurl.com/4fb68xdj

#OrganicSynthesis #stereochemistry #asymmetric #stereoselective #catalysis #MaterialsScience #BJOC 💎🔓

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Leaving Flatland Chemistry

Leaving Flatland Chemistry

Leaving Flatland Chemistry

#Science #Chemistry #Chemicalbonds #Organicchemistry #Stereochemistry

sciencehumor.io/chemistry-memes/leaving-...

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Summary of permeability selection results for the archaeal and hybrid membranes. Top:  the lipid compounds used for vesicle construction and permeability comparisons. Middle and bottom: summary of permeability function. Pentose sugars are notated as pentagons, hexose sugars as hexagons, and amino acids as circles. Arrows indicate permeability function across the various membranes where wider blue (l) or red (d) arrows denote a significant differential enantiomer permeability selection. Key indicates which arrow side represents which enantiomer. Compounds colored orange indicate enantiomer selection that matches the core biochemistry of life. The authors have added glycine here based on results from their previous work. Glycine has no stereochemistry and has been shown to permeate both the archaeal and hybrid membrane

Summary of permeability selection results for the archaeal and hybrid membranes. Top: the lipid compounds used for vesicle construction and permeability comparisons. Middle and bottom: summary of permeability function. Pentose sugars are notated as pentagons, hexose sugars as hexagons, and amino acids as circles. Arrows indicate permeability function across the various membranes where wider blue (l) or red (d) arrows denote a significant differential enantiomer permeability selection. Key indicates which arrow side represents which enantiomer. Compounds colored orange indicate enantiomer selection that matches the core biochemistry of life. The authors have added glycine here based on results from their previous work. Glycine has no stereochemistry and has been shown to permeate both the archaeal and hybrid membrane

Early in the #evolution of life a biochemical network was encapsulated within a membrane compartment. This study shows that specific #membrane forms can select for stereochemical compounds that match the pattern of #stereochemistry used by all known living things @plosbiology.org 🧪 plos.io/4jdyLh1

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Summary of permeability selection results for the archaeal and hybrid membranes. Top:  the lipid compounds used for vesicle construction and permeability comparisons. Middle and bottom: summary of permeability function. Pentose sugars are notated as pentagons, hexose sugars as hexagons, and amino acids as circles. Arrows indicate permeability function across the various membranes where wider blue (l) or red (d) arrows denote a significant differential enantiomer permeability selection. Key indicates which arrow side represents which enantiomer. Compounds colored orange indicate enantiomer selection that matches the core biochemistry of life. The authors have added glycine here based on results from their previous work. Glycine has no stereochemistry and has been shown to permeate both the archaeal and hybrid membrane

Summary of permeability selection results for the archaeal and hybrid membranes. Top: the lipid compounds used for vesicle construction and permeability comparisons. Middle and bottom: summary of permeability function. Pentose sugars are notated as pentagons, hexose sugars as hexagons, and amino acids as circles. Arrows indicate permeability function across the various membranes where wider blue (l) or red (d) arrows denote a significant differential enantiomer permeability selection. Key indicates which arrow side represents which enantiomer. Compounds colored orange indicate enantiomer selection that matches the core biochemistry of life. The authors have added glycine here based on results from their previous work. Glycine has no stereochemistry and has been shown to permeate both the archaeal and hybrid membrane

Early in the #evolution of life a biochemical network was encapsulated within a membrane compartment. This study shows that specific #membrane forms can select for stereochemical compounds that match the pattern of #stereochemistry used by all known living things @plosbiology.org 🧪 plos.io/4jdyLh1

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Summary of permeability selection results for the archaeal and hybrid membranes. Top:  the lipid compounds used for vesicle construction and permeability comparisons. Middle and bottom: summary of permeability function. Pentose sugars are notated as pentagons, hexose sugars as hexagons, and amino acids as circles. Arrows indicate permeability function across the various membranes where wider blue (l) or red (d) arrows denote a significant differential enantiomer permeability selection. Key indicates which arrow side represents which enantiomer. Compounds colored orange indicate enantiomer selection that matches the core biochemistry of life. The authors have added glycine here based on results from their previous work. Glycine has no stereochemistry and has been shown to permeate both the archaeal and hybrid membrane

Summary of permeability selection results for the archaeal and hybrid membranes. Top: the lipid compounds used for vesicle construction and permeability comparisons. Middle and bottom: summary of permeability function. Pentose sugars are notated as pentagons, hexose sugars as hexagons, and amino acids as circles. Arrows indicate permeability function across the various membranes where wider blue (l) or red (d) arrows denote a significant differential enantiomer permeability selection. Key indicates which arrow side represents which enantiomer. Compounds colored orange indicate enantiomer selection that matches the core biochemistry of life. The authors have added glycine here based on results from their previous work. Glycine has no stereochemistry and has been shown to permeate both the archaeal and hybrid membrane

Early in the #evolution of life a biochemical network was encapsulated within a membrane compartment. This study shows that specific #membrane forms can select for stereochemical compounds that match the pattern of #stereochemistry used by all known living things @plosbiology.org 🧪 plos.io/4jdyLh1

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