🔬 Prof. Ying Xia and colleagues highlight recent advances in the #synthesis of axially #chiral cycloalkanes, covering key strategies such as asymmetric allylic substitution, #alkene insertion, #carbene cross-coupling, [2+2] #cycloadditions, and #deracemization.

🔗 Read now: bit.ly/4pCRhTy
#ChemSky

The Taming of a ‘Wild Horse’ Carbene!: Driving Drug Discovery through Lowergy Pharmaceutical Synthesis Associate Professor, Graduate School of Pharmaceutical Sciences, Chiba University Shingo HARADA |... Captivated by the extraordinary reactivity of carbenes—highly activated carbon species that exhibit remarkable chemical activity—Associate Professor Shingo Harada of the Graduate School of Pharmaceuti...

【CHIBADAI NEXT】
The Taming of a ‘Wild Horse’ #Carbene!: Driving Drug Discovery through Low-energy #Pharmaceutical Synthesis

Shingo HARADA, Associate Professor
Graduate School of Pharmaceutical Sciences, #ChibaUniversity

www.cn.chiba-u.jp/en/next_e251...

#DrugDiscovery #Carbon #Research

Scientists Prove 1958 Vitamin B1 Carbene Theory in Water

UC Riverside chemists have directly observed a vitamin B1‑derived carbene stable in water, confirming the 1958 hypothesis, with NMR and X‑ray evidence published in Science Advances. Read more: getnews.me/scientists-prove-1958-vi... #carbene #vitaminb1

synthesis, absorption and emission spectrum, photoluminescence decay of a manganese(I) complex

From sub-picoseconds to 190 nanoseconds! Replacing #iron (II) by #manganese (I) gives record excited state lifetime. The paper in @natcomms.nature.com ‬reports #coherence, #photoluminescence and excited state #electrontransfer. #earth-abundant metal plus simple #carbene #ligand. rdcu.be/eBWsL

Unexpected Hydricity of a Bis-Carbene Iridium Complex Provides Insight into Electronic Structure Impacts on Hydride Donor Ability | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Miller and co-workers @InorgChem #iridium #carbene #bis_mim #hydricity #hydride #steric

Homoleptic Iridium(III) Carbene Complexes with gem-Dimethyl-1,2,4-triazolo[4,3-a]indole Chelates for Blue Organic Light-Emitting Diodes | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Zhang, Chen, Wong, and co-workers @InorgChem #iridium #carbene #OLED

Exploring unique L-shape N-heterobicyclic #carbene #ligand scaffolds with #VincentCesar @lcc-cnrs.bsky.social #icomc2025 #keynote lecture

Synthesis, Structures, Photophysics, and Electroluminescence of Dinuclear Carbene-Au(I)-Amide Complexes Featuring the Through-Space Charge Transfer Excited State | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Li, Chen, and co-workers @InorgChem #gold #carbene #amide #NHC #EL #TADF

Blue-emitting iridium(III) phosphors with functional imidazo[4,5-b]pyridin-2-ylidene cyclometalates: designs aimed at greater steric hindrance Ir(iii) carbene complexes are a class of promising phosphors used in constructing high-performance blue OLEDs. In this work, two series of efficient blue-emitting Ir(iii) carbene complexes, namely, f-...

Happy to share our latest collaborative research on blue-emitting iridium(III) phosphors, featured in the @jmaterchem.rsc.org C HOT Papers Collection! Thanks to all collaborators!
#blue #iridium #carbene #research #OLED

doi.org/10.1039/D5TC...

Super-shielded carbene is stable in liquid water Researchers claim to have validated a decades-old hypothesis formulated by Ronald Breslow by generating a carbene in an aqueous environment

Super-shielded carbene is stable in liquid water #Science #Chemistry #OrganicChemistry #ChemicalResearch #WaterStability #Carbene

SciTech Chronicles. . . . . . . . .May 6th, 2025 We are Volunteers of America. Vol II No 30 371 links Curated Mission Control RSS Feed Wordpress SubStack Comments Buy Me A Coffee New Mol...

SciTech Chronicles. . . . . . . . .May 6th, 2025

bit.ly/stc050625

#EphB1/2 #tyrosine #kinase #inhibitors #carbene #thiamine #B1 #3D-printable #electroencephalogram #continuously #bioadhesive #AMT #mesothelioma #"low-carbon metal oxides" #CO2 #"digital twin" #"3D digital model" #sonar #Magellan

The Careful Combination of Bismuth Compounds and CAAC: Formal Halonium and Nitrenium Transfer via Radical Pathways Fundamental bismuth compounds such as BiCl3 and BiBr(NMe2)2 form simple, colorful adducts with cyclic (alkyl)(amino)carbenes. They undergo facile and selective formal X+ and (NMe2)+ transfer from bis...

Happy to share our recent work in #Bismuth chemistry with prof. Crispin Lichtenberg @Philipps university_Marburg
Many thanks to all the co-authors
DrAhmed Fetoh and prof. Jordi Poater #carbene #radicalchemistry
chemistry-europe.onlinelibrary.wiley.com/doi/full/10....

Peripheral-Carbazole-Group-Functionalized Tetradentate Carbene Platinum(II)/Palladium(II) Phosphorescent Complexes: Synthesis, Structures, and Optical Tuning | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Shi and co-workers @InorgChem #platinum #palladium #carbene #carbazole

Isolation and Reactivity of Carbene-Stabilized Carbon Disulfide Radical Anions | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Wilson, Machan @RJGilliard and co-workers @InorgChem #CAAC #carbene #CS2 #radical_anions

Stabilization of [(N5)2BX]2– and [(N5)2B2X2]2– (X = H, F, Cl, Br) by Conjugation and Hyperconjugation Effects | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Zhang, Schaefer III, and co-workers @InorgChem #boron #carbene #borylene #NBO #LOL #ELF #conjugation #hyperconjufation

In just a decade, #hypervalent iodine and #carbene chemistry has exploded💥New reactions, reagents, and new possibilities. As highlighted by @nievespramirez.bsky.social and Jerome Wasser (@lcsolab.bsky.social), this field is constantly evolving.

#OpenAccess 👉 www.thieme-connect.de/products/ejo...

Low Temperature Emissive Cyclometalated Cobalt(III) Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Bauer and co-workers @InorgChem #cobalt #cyclometalated #carbene #emission #lowT #3MC #DFT

Uncovering diverse reactivity of NHCs with diazoalkane: C–H activation, CC bond formation, and access to N-heterocyclic methylenehydrazine N-heterocyclic carbenes (NHCs) have attracted significant attention due to their strong σ-donating capabilities, as well as their transition-metal-like reactivity towards small molecules. However, the...

Our recent paper at Chemical Science describing diverse reactions of NHCs towards TMSCHN2 #maingroupchemistry #Carbene
doi.org/10.1039/D4SC...