Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

9 months ago

Temperature-dependent interfacial reactions between a sulfide argyrodite solid electrolyte and a lithium metal anode Conventional lithium-ion batteries face increasing demand for higher energy density and improved safety. Lithium (Li) metal all-solid-state batteries are considered a promising solution to meet these ...

📢Temperature-dependent #interfacial reactions between a sulfide argyrodite solid #electrolyte and a #lithium metal anode

Recent #ICF_research from Sangryun Kim et al. at Gwangju Institute of Science and Technology

#Batteries #Chemsky

doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

9 months ago

Modulating optical properties through cation substitution: composition-property relationships in MI3MIIIP3O9N:Eu2+ (MI = Na, K; MIII = Al, Ga, In) Developing phosphors with narrow photoluminescence emission peaks and high chromatic stability holds significant importance in light-emitting diode (LED) display technologies, where a wide color gamut...

📢Don't miss the #OpenAccess #ICF_research featured in our Emerging Investigator series!

🔓by Jakoah Brgoch et al. from University of Houston

#phosphors #LEDs #Inorganic
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Silagermylenation of CO bonds and radical fragmentation of CO2-expanded bis(germylene) by a cyclic (alkyl)(amino)carbene The transformation of the greenhouse gas CO2 into value-added products represents a major contemporary challenge. Low-valent p-block compounds typically react at the oxygen termini of CO2 due to the o...

🔓Recent #OpenAccess #ICF_research
👉Silagermylenation of C=O bonds and radical fragmentation of CO2-expanded bis(germylene) by a cyclic (alkyl)(amino)carbene
#Inorganic
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

The timeless relevance of size-match selectivity in macrocyclic Fe(III) complexes Given the recent emergence of Fe(iii) complexes as promising MRI contrast agents, there has been significant interest in understanding their coordination chemistry, particularly the delicate balance a...

📢Check out the #OpenAccess research by Zsolt Baranyai, Lorenzo Tei et al.

The timeless relevance of size-match selectivity in macrocyclic Fe(iii) complexes
#ICF_research #inroganic
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Design of an inflorescence-type phosphorus-doped (Ni,Co)–molybdate architecture with an atomically thin cobalt oxide layer for high-efficiency energy storage systems High-performance asymmetric supercapacitors (ASCs) need to promote the diffusion of the electrolyte into the electrode, a process that is governed by the electron transfer kinetics and morphology of t...

#ICF_research paper by Do-Heyoung Kim et al.

👉Design of an inflorescence-type phosphorus-doped (Ni,Co)–molybdate architecture with an atomically thin cobalt oxide layer for high-efficiency #energy storage systems
#supercapacitor

doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Tailoring high-entropy borides for hydrogenation: crystal morphology and catalytic pathways The high-entropy boride (HEB) Al0.2Nb0.2Pt0.2Ta0.2Ti0.2B2, with its unique crystal structure and high coordination (platinum coordinated to 12 boron atoms), has been shown in our previous work to exhi...

📢Check out the research by from Ting Wang, Michael T. Yeung et al. @albany.edu

👉Tailoring high-entropy #borides for #hydrogenation: #crystal morphology and #catalytic pathways
#ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Interfacial defect engineering to boost deep-ultraviolet photodetection based on a wide-bandgap semiconductor heterostructure Although wide-bandgap semiconductors have emerged as a valuable class of deep-ultraviolet-sensitive materials, showing great potential for next-generation integrated devices, achieving…

👉 Interfacial defect engineering to boost deep-ultraviolet photodetection based on a wide-bandgap semiconductor heterostructure

📢 Recent #research from our editorial board member, Xianran Xing's group for celebrating the 10th anniversary of ICF
#ICF_research #Inorganic

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Insights for controlling plutonium behavior in hydrochloric acid solutions Advancing understanding of aqueous chemistry for plutonium is important because it impacts energy production, environmental management, and national security. Unfortunately, plutonium's aqueous chemis...

👉Don't miss the interesting #research by Stosh A. Kozimor et al. from Los Alamos National Laboratory

🔓Insights for controlling #plutonium behavior in hydrochloric acid solutions
#Chemsky #ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

o-Carborane decorated diboron-embedded multi-resonance TADF compounds featuring narrowband emission Simultaneously achieving high luminescence quantum efficiency and narrowband emission in o-carboranyl luminophores remains a significant challenge for enhancing color purity and extending their applic...

👉Recent #research by Jaehoon Jung, Min Hyung Lee et al. from University of Ulsan

o-Carborane decorated diboron-embedded multi-resonance TADF compounds featuring narrowband emission
#optoelectronic #inorganic #ICF_research

doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Half-sandwich scandium methylidenes AlMe3 sticks, GaMe3 quits. A series of Lewis acid stabilized scandium methylidenes with commercially available cyclopentadienyl ligands CpR (CpR = C5Me5 (Cp*), C5Me4SiMe3 (Cp′)) were synthesized. The-...

#OpenAccess #research in ICF by Reiner Anwander et al.

Half-sandwich scandium methylidenes
#ICF_research #inorganic
Read it for free: doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Cumulative 2c–2e vs. 3c–2e π-back donations: conformation preferences in germylene gold(I) complexes The first homoleptic and heteroleptic cationic germylene-gold(i) complexes 3, 4, and 7 have been synthesized and structurally characterized, accompanied by the discovery of novel types of π-back donat...

#Research article by Jiaxin Chen, Liliang Wang et al.
Cumulative 2c–2e vs. 3c–2e π-back donations: conformation preferences in #germylene gold(i) complexes
🧪 #Inorganic #ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

A DNA aptamer for trivalent lanthanide ions with low nanomolar affinity Lanthanides are extremely important for a variety of technological applications. In this work, DNA aptamers were selected using the library-immobilization method (capture-SELEX) with Tb3+ and Ce3+ as ...

🔓Check out recent #OpenAccess research -- A DNA #aptamer for trivalent #lanthanide ions with low nanomolar affinity
🧪 #Chemsky #ICF_research #Inorganic
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Exploring the photophysics and excited state reactivity of [Ru(4,4′-BTFMB)2 (L)]2+ complexes (L = bpy, phen, TAP) as photodynamic therapy agents: a theoretical investigation In this work, we explore the excited states of three different [Ru(4,4′-BTFMB)2 (L)]2+ complexes (C1: L = bpy (2,2′-bipyridine); C2: L = phen (1,10-phenantroline); and C3: L = TAP (1,4,5,8-tetraazaphe...

📢Check out the #research by Willian Ricardo Rocha et al.

👉Exploring the photophysics and excited state reactivity of [Ru(4,4′-BTFMB)2 (L)]2+ complexes (L = bpy, phen, TAP) as photodynamic therapy agents: a theoretical investigation

#Chemsky #Inorganic #ICF_research

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Exploring protonation sites with cation-responsive polyethylene glycol (PEG) tethers in [FeFe]-hydrogenase mimics Mimics of [FeFe]-hydrogenases having two [(μ-adt)Fe2(CO)6] moieties linked through 1,2,3-triazole rings with polyethylene glycol (PEG) chains [(–OCH2CH2O–)4 (7) and (–OCH2CH2O–)5 (8)] are able to coor...

🔓Don't miss the #OpenAccess #research article by Miguel A. Sierra et al.
👉Exploring protonation sites with cation-responsive polyethylene glycol (PEG) tethers in [FeFe]- #hydrogenase mimics
#Chemsky #Inorganic #ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

10 months ago

Low-valent tantalum/gold clusters: oxidation, protonation, and C–H activation Gold-based catalysts are topical heterogeneous and molecular species, the chemical diversity of which can be expanded through heterometal doping. Herein, we leverage a carbonyl-free metal–metal salt m...

🔓Low-valent tantalum/gold #clusters: oxidation, protonation, and C–H activation

👉Don't miss the #OpenAccess #research by Michela L. Maiola and Joshua A. Buss from University of Michigan@umich.edu
#Chemsky #Inorganic #ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Comparison of PGSE NMR and ESI-MS measurements on methylaluminoxane PGSE NMR and ESI-MS studies of different grades of hydrolytic methylaluminoxane (MAO) demonstrate a correlation between the average dimensions and anion distribution of MAO. This correlation is reveal...

👉Take a look at the OpenAccess research #Chemsky #Inorganic #ICF_research

🔓Comparison of PGSE NMR and ESI-MS measurements on #methylaluminoxane

doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Enhanced negative permittivity by A-site heterovalent ion doping in La1−x−yCaxKyMnO3 perovskites Adjusting the concentration of free carriers is a direct strategy to achieve ideal negative permittivity. Employing chemical methods for atypical ion doping is an effective approach to regulate the co...

📢Recent #research from Shouhua Feng et al. at Jilin University

👉Enhanced negative #permittivity by A-site heterovalent ion doping in La1−x−yCaxKyMnO3 #perovskites
#Chemksy #Inorganic #ICF_research

doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Albumin-targeted oxaliplatin(IV) prodrugs bearing STING agonists The anticancer platinum complex oxaliplatin exerts its activity through DNA damage and immune-stimulatory mechanisms, but is associated with adverse treatment side effects. Platinum(iv) complexes repr...

📢Don't miss the #OpenAccess #research by Christian R. Kowol et al. @univie.ac.at

👉#Albumin-targeted oxaliplatin(iv) #prodrugs bearing STING #agonists

#Chemsky #ICF_research #Inorganic #anticancer
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Dibenzocyclooctatetraene based poly-Lewis-acids: flapping hosts for multidentate guests A synthetic route to flapping poly-Lewis acids (PLAs) based on dibenzocyclooctatetraene was developed. The reactivity of tetradentate boron and aluminium containing PLAs towards various Lewis bases (L...

👉Dibenzocyclooctatetraene based poly-Lewis-acids: flapping hosts for multidentate guests

🔓 #OpenAccess research by Norbert W. Mitzel et al. from Bielefeld University

#Chemsky #Inorganic #ICF_research

doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

A platinated prodrug leveraging PROTAC technology for targeted protein degradation and enhanced antitumor efficacy Proteolysis targeting chimeras (PROTACs), which catalytically degrade disease-related proteins, can overcome the limitations of traditional small-molecule inhibitors and thus have revolutionized the f...

👇Read the hot #research by Guangyu Zhu et al. from City University of Hong Kong

🔥A platinated #prodrug leveraging PROTAC technology for targeted protein degradation and enhanced #antitumor efficacy
#Chemsky #Inorganic #bioinorganic #ICF_research #Platinum

doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

The impact of “empty-corner” tetrahedra in the synthesis of MFI type zeolites: unveiling selenium stereoactivity This study investigates the impact of selenium in different oxidation states, specifically Se6+ and Se4+, on the structural features of MFI-type zeolites. Se4+ is characterized by trigonal pyramidal c...

👉Recent #research by Svetlana Mintova et al. at Université de Caen Normandie

The impact of “empty-corner” tetrahedra in the synthesis of MFI type #zeolites: unveiling selenium stereoactivity

#Chemsky #Inorganic #ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Doubly crossed supercoils built by cooperative anion and metal coordination Supercoiled structures with multiple, continuous “figure-eight” conformations, such as complex DNA plectonemes, are ubiquitous and play vital roles in biological systems. In comparison, synthetic smal...

🔥Check out the hot research reported the doubly crossed #supercoils built by cooperative anion and metal #coordination
#Chemsky #Inorganic #ICF_research #biological

👉 doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Phosphole oxide-based cyclometalated platinum(II) β-diketonate complexes for cooperative self-assembly and solution-processable resistive memories with excellent stability A new class of neutral phosphole oxide-based cyclometalated platinum(ii) β-diketonate complexes has been demonstrated to show cooperative self-assembly in THF–water mixtures, modulated by the directio...

👉Check out the #research by Vivian Wing-Wah Yam et al.

Phosphole oxide-based cyclometalated platinum(ii) β-diketonate complexes for cooperative self-assembly and solution-processable resistive memories with excellent stability
#Chemsky #Inorganic #ICF_research
doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Gallium incorporation in blue-emitting In1−xGaxP alloy quantum dots facilitated by monomeric gallium precursors Demand for environmentally friendly quantum dots (QDs) in wide color-gamut displays has led to successful development of red- and green-emitting InP QDs with outstanding optical properties. While prog...

👉Gallium incorporation in blue-emitting In1−xGaxP alloy quantum dots facilitated by monomeric gallium precursors

🔓Don't miss the #OpenAccess #research from Hyeonjun Lee, Doh C. Lee et al.
#Chemsky #Inorganic #QDs #LEDs #ICF_research
doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

The hydrolytic stability of the human tubulin α 1A protein fragment – a potential reason for the role of metal ions in the development of neurodegenerative diseases Alpha-tubulin proteins are recognised as key components in the process of cell division due to their role in dimerisation and polymerisation, which results in the formation of microtubules in eukaryot...

👉Check out this #research by Katalin Várnagy et al.

The hydrolytic stability of the human tubulin α 1A protein fragment – a potential reason for the role of metal ions in the development of #neurodegenerative diseases
#Chemsky #Inorganic #ICF_research

doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Guest-induced gate-opening in a flexible MOF adsorbent that exhibits benzene/cyclohexane selectivity We report the synthesis of a 2-fold interpenetrated primitive cubic (pcu) topology network, X-pcu-11-Zn, formulated as [Zn2(DMTDC)2(dpb)] (H2DMTDC = 3,4-dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid; dpb = 1,4-di(pyridin-4-yl)benzene). Upon removal of solvent molecules from the as-synthesised form, X-pcu-11-

👇Don's miss the recent #OpenAccess #research from Ai-Xin Zhu, Michael J. Zaworotko et al. @unioflimerick.bsky.social

🔓Guest-induced gate-opening in a flexible MOF adsorbent that exhibits benzene/cyclohexane selectivity

#Chemsky #Inorganic #ICF_research

doi.org/10.1039/D5QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Rare earth double perovskites for underwater X-ray imaging applications Lanthanide metal halide double perovskites (Ln-MHDPs) are promising scintillator materials due to their outstanding luminescence properties and high X-ray absorption cross-sections. With the growing d...

🔊Check out the #research from Qingsong Hu, Jiawen Xiao, Omar F. Mohammed et al.

👉Rare earth double #perovskites for underwater X-ray imaging applications
#Chemsky #Inorganic #ICF_research
doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Tuning photochromism and photomagnetism via diverse bimetallic cyanido viologen hybrid materials The integration of photochromism and photomagnetism is of great significance for developing photo-responsive multifunctional materials. Herein, we successfully synthesized four cyanido-bridged bimetal...

👇New #research from the Editor-in-chief, Prof. Song Gao et al.

Tuning photochromism and photomagnetism via diverse bimetallic cyanido viologen hybrid materials

#Chemsky #magnetism #Inorganic #ICF_research

doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Fabrication of a p-Ni0.8Cu0.2WO4/n-Si heterojunction diode and its 1 MHz rectifier operation Herein, we report on the fabrication of a heterostructure diode adopting a p-Ni0.8Cu0.2WO4 oxide/n-Si junction and its demonstration toward a high-speed rectifier circuit up to 1 MHz operation. Novel ...

👉Fabrication of a p-Ni0.8Cu0.2WO4/n-Si #heterojunction diode and its 1 MHz rectifier operation

by Min Suk Oh, Kimoon Lee and colleagues

#Chemsky #Inorganic #ICF_research #oxide #electronics
doi.org/10.1039/D4QI...

Inorganic Chemistry Frontiers

@inorgchemfront.rsc.org

11 months ago

Construction of Ni–Co alloy/zeolite nanosheet catalysts for the hydrodeoxygenation of fatty acids to alkanes Hydrodeoxygenation of bio-lipids into renewable alkanes is a promising strategy to substitute fossil resources. Bifunctional metals/zeolites have demonstrated high performance in hydrodeoxygenation re...

👉Check out the #research from Jihong Yu for ICF 10th Anniversary Collection!

Construction of Ni–Co alloy/ #zeolite nanosheet #catalysts for the #hydrodeoxygenation of fatty acids to alkanes
#Chemsky #ICF_research #Inorganic

doi.org/10.1039/D4QI...