Shining new light on #epoxides 🔬 Huang & co-workers unveil a visible-light-driven route to α-amino epoxides via an oxa-π,σ-methane rearrangement🧪 Mild, selective, and versatile—breaking past traditional synthetic limits
#photochemistry
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Controlling epoxide #cyclizations like never before🌀
Vanderwal & co-workers explore α-alkoxy #epoxides in Nugent–RajanBabu reductive cyclizations, revealing how α-oxygen protecting group size dictates 6-endo vs 5-exo outcomes⚗️
#TotalSynthesis
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Following successful small-scale demonstrations of reactions between specialty #epoxides, the customer requested larger quantities of the resulting products for further evaluation. See how AVN assembled appropriate reaction #apparatus... avncorp.com/blogs/the-av...
Explore the power of asymmetric #RingOpening of #epoxides ! Recent advances in #TransitionMetal-catalyzed reactions, highlighted in the review by Zhang, Guo and co-workers, offer high efficiency & selectivity in creating valuable chiral building blocks ✨
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Understanding the Effect of M(III) Choice in Heterodinuclear Polymerization Catalysts | Inorganic Chemistry pubs.acs.org/doi/10.1021/... Williams and co-workers @InorgChem #Al #Fe #Co #K #ROCOP #epoxides #CO2 #anhydrides #polycarbonates #polyesters #catalysis